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Book synopsis

Cel' raboty sostoyala v razrabotke novyh strategij sinteza soedinenij indolizinovogo ryada i ih nejtral'nyh, kationidnyh i mezoionnyh geteroanalogov, v izuchenii stroeniya i reakcionnoj sposobnosti poluchaemyh soedinenij, a takzhe v vyyavlenii veshhestv s poleznymi dlya prakticheskogo ispol'zovaniya svojstvami. Osnovnymi zadachami raboty yavlyalis': (1) Razrabotka puti sinteza 6(8)-nitroindolizinov, issledovanie ih reakcij s jelektrofilami i dienofilami i ih reciklizacij v indoly. (2) Poisk putej sinteza indolizinov s geteroatomom u S-5, sposobnyh k "obychnomu" nukleofil'nomu zameshheniju. (3) Issledovanie mehanizma i granic primenimosti ranee neizvestnoj reciklizacii kondensirovannyh oxazolov (s annelirovannym po svyazi C=N azinovym ciklom) v pirroly, privodyashhej k 5-zameshhennym indolizinam, ih kondensirovannym proizvodnym i aza-analogam. (4) Obshhij analiz regioselektivnosti raskrytiya kationov 1,3-azolopiri(mi)diniya pod dejstviem nukleofilov. (5) Analiz shodstva solej oxazolo[3,2-a]piridiniya i N-fenacil-2-Hal-piridiniya i novyh perspektiv ispol'zovaniya v sinteze. (6) Razrabotka strategij sinteza maloizuchennyh mezoionnyh azolopiridinov issledovanie ih stroeniya, svojstv i perspektiv primeneniya.

Book details

• Full title: Novye sinteticheskie strategii v himii indolizina i ego analogov. Tom 1
• Subtitle: Metody sinteza i reakcionnaya sposobnost' indolizinov i ih analogov
• Author: Evgenij Babaev
• Language: Russian
• Binding: Paperback
• Number of pages: 332
• EAN: 9783659951077
• ID: 15201047
• Publisher: LAP Lambert Academic Publishing
• Weight: 512 g
• Dimensions: 220 × 150 × 20 mm
• Published: 2016

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